Some interesting results. Perhaps the design of the PA did change the voltage characteristics between the Mk-1 and Mk-2, though I understood the changes to be more about preventing spurious (and damaging) oscillations at low voltage when the internal batteries were in use. There is no question, I would hope, that as you increase the supply voltage the losses (in W) increase and therefore case heating becomes a progressively greater problem.
Let’s look in a bit more detail at the discharge characteristics of an LiPo battery. The nominal cell voltage is 3.7V, so a three cell pack is nominally 11.1V. Fully charged (no load) each cell is 4.2V (12.6V for the battery) and fully discharged (on load) 3V per cell (9V).
Now let’s do the same for a lead acid battery. Nominal cell voltage is 2V, so a 6 cell SLAB is nominally 12V. Fully charged (no load) each cell is 2.3V (13.8V for the battery) and fully discharged (on load) 1.75V per cell (10.5V).
Both types of battery have extremely low internal resistance, though that of a LiPo battery is somewhat lower. At the current levels we deal with, internal resistance is not really a factor. Both batteries have a fairly linear discharge level vs voltage profile but the LiPo battery discharges over a wider voltage range, which is potentially a disadvantage.
So much for numbers. What about practice?
I used to use SLABs on my FT817 and I still do, on the odd occasion that I NEED 13.8V because I am also using my 50W linear amp. I found that with a 2.8Ah SLAB the voltage would settle down to around 12.5V quite quickly and stay close to that figure until the battery was close to exhaustion.
With LiPo batteries, I find that the voltage settles quickly down to around 12V and discharges very slowly down to 11.8V before dropping off very quickly as the point of exhaustion is reached.
So practically we are only talking of a difference of between 0.5V and 0.7V across the useful discharge range of the two battery types. If we refer back to the various figures given above, we can see that makes very little difference to the power output of an FT817.
But what a difference there is between the two technologies for equivalent capacity batteries in terms of the weight you have to carry and the space taken up in your rucksack!